I have both Gotham 13.2 final and latest SPMC version on mine and 13.2 runs great with either c02 or confluence. Spmc runs good but I haven't really tested thoroughly yet. It's available on Amazon or Google Play if the Ouya is rooted, if not, you can sideload it from here http://spmc.semperpax.com/
I have a problem I have got Gotham on the Ouya but I have a problem I am getting this message: Failed to import Metahandlers. A component needed by Ic*f*lms is missing on your system. Please visit www.xbmchub.com for support
The only other thing I've seen about this is to do a Fresh Start, but you just installed this right?
So--not sure if that would help.
The only other suggestion I have is to turn on Debugging and post a link to your log here.
Maybe someone could help troubleshoot why this is happening.